This can be configured in the user roles. This can be configured for any bookable resource: rooms, desks or parking spaces.
You can combine multiple user roles for your users where locations or spaces and different days of the week will be included and excluded.
Please check the example below:
You can create one user role for the persons who will be allowed to make bookings on (for example) Mondays in the specific meeting rooms. In the location you can include the rooms that are allowed to be booked and then select the days of the week.
Then create another user role where you will exclude these rooms on Mondays and include all the rest of the resources and assign it to the rest of the users. With this user role all your users will be able to make bookings in all resources (rooms, desks) on Mondays except in those two meeting rooms excluded in the previous user role.
Create another role where you will allow all resources including these rooms to be booked by everyone in the other working days so they can be able to make bookings on other working days.
You can check the article Assing roles to multiple users for more information on how to assign these roles to your users.